Terphenyl

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This also led to the first alternate form of meta-terphenyl synthesis, which involved passing gaseous benzene and toluene through a hot glass tube. By the s, focus had shifted to experimenting with the reactivity of meta-terphenyl and its potential use as a ligand. The first verified modified version of meta-terphenyl was created in by Arthur Wardner and Alexander Lowy and led to the creation of nitro-substituted meta-terphenyls as well as amino-meta-terphenyls from the oxidation of the nitro-substituted compounds. Breadsher and I. Swerlick publishing a review of all known reactions that meta-terphenyl could undergo. Ames also wrote an article detailing not only reactions of meta-terphenyls, but also covering all the different experimental methods to obtain meta-terphenyl known at the time. During this time, the method of producing meta-terphenyl had remained the same.

Terphenyl

Terphenyls are a group of closely related aromatic hydrocarbons. Also known as diphenylbenzenes or triphenyls , they consist of a central benzene ring substituted with two phenyl groups. There are three substitution patterns : ortho -terphenyl, meta -terphenyl , and para -terphenyl. Commercial grade terphenyl is generally a mixture of the three isomers. This mixture is used in the production of polychlorinated terphenyls , which were formerly used as heat storage and transfer agents. One example is atromentin , a pigment found in some mushrooms. These natural p -terphenyls are better described as diphenylquinones or diphenylhydroquinones. Some m-terphenyl compounds occur in plants. Contents move to sidebar hide. Article Talk. Read Edit View history. Tools Tools. Download as PDF Printable version.

Novel terphenyl methods have continued to be developed to this day. Another relevant field of study where meta-terphenyls have shown significant use is organometallics, terphenyl.

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This also led to the first alternate form of meta-terphenyl synthesis, which involved passing gaseous benzene and toluene through a hot glass tube. By the s, focus had shifted to experimenting with the reactivity of meta-terphenyl and its potential use as a ligand. The first verified modified version of meta-terphenyl was created in by Arthur Wardner and Alexander Lowy and led to the creation of nitro-substituted meta-terphenyls as well as amino-meta-terphenyls from the oxidation of the nitro-substituted compounds. Breadsher and I. Swerlick publishing a review of all known reactions that meta-terphenyl could undergo.

Terphenyl

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All rights reserved. In , however, G. Meta-terphenyl continues to play an important part of organometallic chemistry , as well as main group chemistry, due to its kinetic stabilization of molecules and its thermodynamic influence on the energies between molecules. Categories : Aromatic hydrocarbons Phenyl compounds. Contents move to sidebar hide. Woods and Irwin Tucker put forth an alternative method. PMID Tools Tools. Chemical Reviews. Journal of the Chemical Society, Transactions. In other projects. H , H , H , H Goncharova, Axlexander N. Chemical formula. CAS Number.

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Go To: Top , References , Notes. ISSN Precautionary statements. Cambridge: The Royal Society of Chemistry. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. EC Number. These natural p -terphenyls are better described as diphenylquinones or diphenylhydroquinones. The Monochloro and Monobromo Derivatives". Leskin, Natalia A. S2CID Chemical Reviews. Contents move to sidebar hide.